Carbon radicals are attractive intermediates for organic synthesis because of their diversity and high reactivities. In this research, we realized radical C-C bond formation reactions using alcohols ...
CORRECTION: This story was updated on April 21, 2016, to clarify that the method described was not the first radical-based route to chiral quaternary carbon centers. The method is the first route ...
Organocatalysts consisting of organic compounds without metal elements are receiving much attention as next generation catalysts in the hope of reducing environmental burden and coping with exhaustion ...
Making molecules with quaternary carbon bonds—four carbons attached to a central C—is tricky but necessary for medicinal chemists. Quaternary C bonds have a discrete shape, Princeton University ...
ESR spectra of short-lived radicals made by photolysis at room temperature of acidic alcoholic solutions of imidazole, 1-methylimidazole, and 4(5)-methylimidazole containing acetone or hydrogen ...
Organocatalysts consisting of organic compounds without metal elements are receiving much attention as next generation catalysts in the hope of reducing environmental burden and coping with exhaustion ...